BARTHLOTT, WILHELM AND CHRISTOPH NEINHUIS.* Botanisches Institut und Botanischer Garten, Meckenheimer Allee 170, D-53115 Bonn, Germany. - The Lotus-Effect: a paradigm for the use of a natural design for technical application.
.
The surfaces of leaves and shoots are covered by a thin extracellular
membrane, the cuticle. It constitutes of an insoluble polymer (cutin)
and soluble lipids, usually called "waxes". They are
embedded into the polymer and are also present on the surface. In most
plants, these epicuticular waxes form characteristic microstructures
due to self-organisation. Generally they are regarded as crystals. The
epicuticular wax layer is a multifunctional interface between plant
and environment, influencing air flow or light reflexion and often
causes high water repellency. Water which is applied to such surfaces
forms small droplets rolling free over the leaves. As a new, hitherto
overlooked feature we were able to show that water-repellency is
connected to an almost perfect self-cleaning ability of leaves. Since
this effect can be beautifully demonstrated with the large peltate
leaves of INelumbo nucifera/I, the sacred lotus, we called it
Lotus-Effect. The Lotus-Effect is present in a large number of plants
and depends on microstructured hydrophobic surfaces. While in smooth
surfaces contact angles reach up to 110°, roughness in the dimensions
of micrometers causes super-hydrophobicity with contact angles up to
170°. In such cases the area for adhesion for water is minized and air
is enclosed between droplets and the individual wax crystals. The same
holds true for particles. Again, the contact area between particle
and rough surface is minimized resulting in the adhesion of particles
to the water droplets that roll over the leaf surface. Independant of
size and chemical nature, particles are removed from such
super-hydrophobic surfaces with only a small amount of rain. Since the
Lotus-Effect depends only on physico-chemical properties of the leaves
it can be transferred to technical surfaces and may lead to biomimetic
self-cleaning paints or other surface coverings in the near future.
Key words: contamination, cuticle, epicuticular waxes, Lotus-Effect, self-cleaning, wettability